刘秋华，女，1981年出生，博士，副教授，硕士研究生导师，必威西蒙体育官网化学系教师。2018.02-2019.02美国内布拉斯加大学林肯分校访问学者。主要从事生物无机化学和金属有机化学及相关的研究，围绕金属配合物功能分子的设计、合成、性能，以及相关组装体系开展了一系列研究工作。主持国家自然科学基金青年项目1项、湖南省教育厅重点科学研究项目1项、betway必威西汉姆联官网理论有机化学与功能分子教育部重点实验室开放基金1项，近年来主要参与国家自然科学基金项目4项。2015年获湘潭市自然科学优秀学术论文二等奖1项。近年来研究成果发表在《J. Am. Chem. Soc. 》、《Inorg. Chem.》、《Phys. Chem. C》、《Org. Biomol. Chem.》、《J. Phys. Chem. B》、《Org. Lett.》、《Chem. Eur. J.》、《Eur. J. Inorg. Chem. 》、《Chin. J. Chem》等权威学术刊物上。授权澳大利亚革新专利1项、国家发明专利2项。
联系方式：
Email: liuqiuhua@hnust.edu.cn
主持的科研项目：
[1] 国家自然科学基金青年项目，大环变形对卟啉中心钴(Ⅱ)离子电子结构的调控（No.21602054），20万，2017.01-2019.12，结题；
[2] 湖南省教育厅重点科学研究项目，碳纳米管管径和管长对其光谱红移影响的理论研究(No. 20A195)，8万，2020.10-2023.09，在研；
[3] 理论有机化学与功能分子教育部重点实验室开放基金，单氧杂核修饰卟啉对低价铜(I)离子的电荷效应（No.E21509），1.5万，2015.01-2016.12
发表的主要论文：
[1] Jinjin Zhang, Min Tang, Dilong Chen, Binghua Lin, Zaichun Zhou,* Qiuhua Liu*, Horizontal and Vertical Push Effects in Saddled Zinc Porphyrin Complexes: Implications for Heme Distortion, Inorg. Chem. 2019, 58, 2627−2636.
[2] Brian Pattengale, Qiuhua Liu, Wenhui Hu, Sizhuo Yang, Peilei He, Sir Lawrence Tender, Yingqi Wang, Xiaoyi Zhang, Zaichun Zhou,* Jian Zhang,* Jier Huang*, Selective Excited-State Dynamics in a Unique Set of Rationally Designed Ni Porphyrins，Phys. Chem. C. 2019, 123, 17994−18000.
[3] Qiuhua Liu, Jinjin Zhang, Min Tang, Yan Yang, Jian Zhang*, Zaichun Zhou, Geometric Deconstruction of Core and Electron Activation of a π-System in a Series of Deformed
Porphyrins: Mimics of Heme, Org. Biomol. Chem., 2018, 16, 7725–7736.
[4] Jingzhi Lu, Brian Pattengale, Qiuhua Liu, Sizhuo Yang, Wenxiong Shi, Shuzhou Li,*Jier Huang,* Jian Zhang*, Donor−Acceptor Fluorophores for Energy-Transfer-Mediated Photocatalysis, J. Am. Chem. Soc. 2018, 140, 13719−13725.
[5] Min Tang, Yan Yang, Shaowei Zhang, Jiafu Chen, Jian Zhang, Zaichun Zhou,* Qiuhua Liu*, Electron Transfer and Geometric Conversion of Co−NO Moiety in Saddled Porphyrins: Implications for Trigger Role of Tetrapyrrole Distortion, Inorg. Chem. 2018, 57, 277−287.
[6] Qiuhua Liu, Min Tang, Wennan Zeng, Xi Zhang, Jianxiu Wang,* Zaichun Zhou*, Optimal Size Matching and Minimal Distortion Energy: Implications for Natural Selection by the Macrocycle of the Iron Species in Heme, Eur. J. Inorg. Chem. 2016, 5222–5229.
[7] Qiuhua Liu, Xi Zhang, Wennan Zeng, Jianxiu Wang,* Zaichun Zhou*, Origin of d-π Interaction in Cobalt(II) Porphyrins under Synergistic Effects of Core Contraction and Axial Ligation: Implications for a Ligand Effect of Natural Distorted Tetrapyrrole. Chin. J. Chem. 2016, 34, 910—918.
[8] Zaichun Zhou,* Min Tang, Qiuhua Liu,* Xi Zhang, Xiaochun Zhou, Formation of π-Cation Radicals in Highly Deformed Copper(II) Porphyrins: Implications for the Distortion of Natural Tetrapyrrole Macrocycles, Eur. J. Inorg. Chem. 2016, 3585–3591.
[9] Qiuhua Liu, Xiaochun Zhou, Haomin Liu, Xi Zhang, Zaichun Zhou*, Fractional transfer of a free unpaired electron to overcome energy barriers in the formation of Fe4+from Fe3+during the core contraction of macrocycles: implication for heme distortion. Org. Biomol. Chem., 2015, 13, 2939–2946.
[10] Qiuhua Liu, Xi Zhang, Wennan Zeng, Jianxiu Wang,* Zaichun Zhou*, Fine-Tuning of Electronic Structure of Cobalt(II) Ion in Nonplanar Porphyrins and Tracking of a Cross-Hybrid Stage: Implications for the Distortion of Natural Tetrapyrrole Macrocycles. J. Phys. Chem. B 2015, 119, 14102−14110.
[11] Zaichun Zhou*, Xiaochun Zhou, Qiuhua Liu,* Xizhang, Haomin Liu, Fixation of Zinc(II) Ion to Dioxygen in a Highly Deformed Porphyrin: Implications for the Oxygen Carrier Mechanism of Distorted Heme, Org. Lett. 2015, 17, 4078-4081.
[12] Zaichun Zhou,* Xi Zhang, Qiuhua Liu,* Ziqiang Yan, Chengjin Lv, Ge Long, Geometry and Temperature Dependence of meso-Aryl Rotation in Strained Metalloporphyrins: Adjustable Turnstile Molecules, Inorg. Chem. 2013, 52, 10258−10263.
[13] Zaichun Zhou,* Qiuhua Liu, Ziqiang Yan, Ge Long, Xi Zhang, Chenzhong Cao,* Rongqing Jiang, Conversion of Electron Configuration of Iron Ion through Core Contraction of Porphyrin: Implications for Heme Distortion, Org. Lett., 2013, 15, 606-609.
授权发明专利：
[1] Qiuhua Liu, Huiyang Xu，Zaichun Zhou, Siwei Zhang. Heme ligand mimetics and synthesis method, 澳大利亚革新专利，专利号： 2020103151；
[2] 刘秋华，唐敏，周再春， 新型水溶性八羟基卟啉的一步合成方法, 专利号：ZL201510945703.6
[3] 周再春，唐敏，刘秋华，电压梯度法检测气体中衡量组分的方法，专利号：ZL201510945811.3
